So I think airships are cool and my world already has a source for crazy physics-breaking materials, and I thought, why not add another one to make airships slightly better? (Which based off other answers I've browsed caps out at 6-7% better compared to helium).
Introducing vacium (because the scientists that discovered it were not feeling creative).
Introduction to Vacium
Vacium is a low density liquid (merging with other globs of vacium in contact with it). It's produced in relatively small amounts by an exotic flying creature in this foreign land.
Properties
When not contained properly (exposed to gas/not in contact with null-vacium), vacium will begin to "intake vacuum" until it creates a bubble of near-perfect vacuum trapped inside a thin film of vacium (which is technically part force-field since the thickness would be measured in micros). I imagined it to be like a drop of soap, except it's self-inflating.
The surface of the vacium bubble is almost frictionless. It will also exert an mild overpressure similar to an inflated balloon when pressed on and will deform to some extent without rupturing.
Similar to a soap bubble, objects puncturing it will not rupture it but will rather just slide through before being subject to an increasing pushing force attempting to maintain its internal vacuum. In the event of rupturing, vacium in contact with each other will rapidly pull back toward its liquid glob state before inflating again as soon as it gains enough cohesion.
Tentative maths
A gram of inert vacium at 1 atm will have a density of 0.15/mL. Once rendered non-inert, it will expand to a 100 liter (100,000 cm3) spherical volume. Overall, compared to one gram of hydrogen, it is 1/9th the density and the values can be changed. The effective density is 0.01g/L, with a lifting force of 1.282 kg/m3 (assuming the density of air being 1.292).
Nullification w/ Null-Vacium
Contact of null-vacium (also produced by the exotic creature to regulate its own flight) with the vacium bubble will cause the vacium to leak and the vacium will revert to its liquid form until removed. The null-vacium will not mix with the vacium and its nullification property propagates through the vacium itself.
Issue
Now that I have this substance, I'm worried about what other "game-breaking" uses it might have.
Ideally, it's limited to just the cool airship that could potentially lower costs enough to steal part of ocean shipping's pie and reduce costs of airship cruises, but from my experience this kind of physics-breaking material usually have applications I didn't think of.
I also think this violates the second law of thermodynamics, but I'm not smart enough to know what the implications are.
The question is what other applications does this substance have? I considered parachutes, but it would depend on how quickly the vacium "inflates."